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Electronic and Photoelectron Spectroscopy
Fundamentals and Case Studies

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  • Date Published: April 2011
  • availability: Available
  • format: Paperback
  • isbn: 9780521520638

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  • Electronic and photoelectron spectroscopy provides extraordinarily detailed information on the properties of molecules. This book presents the basic principles and experimental techniques employed in electronic and photoelectron spectroscopy. A major feature is the extensive use of case studies to illustrate how spectra are assigned and how information can be extracted. The text is intended for advanced undergraduate and graduate students studying courses in spectroscopy.

    • Describes the theory and experimental techniques behind electronic and photoelectron spectroscopy
    • Extensive use of case studies allows the reader to follow the reasoning employed in the assignment of molecular spectra and how the information is extracted from the spectrum
    • Describes spectroscopic techniques
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    Reviews & endorsements

    "For a scientist with a solid math and chemistry background, this is an excellent book on spectroscopy. Highly recommended." CHOICE

    "This text bridges the gap between the basics and cutting edge applications of electronic spectroscopy at a level appropriate for upper-level undergraduates and junior graduate students...clearly written and easily digested." - Journal of the American Chemistry Society, Caroline Chick Jarrold, Indiana University

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    Product details

    • Date Published: April 2011
    • format: Paperback
    • isbn: 9780521520638
    • length: 302 pages
    • dimensions: 244 x 170 x 16 mm
    • weight: 0.49kg
    • availability: Available
  • Table of Contents

    Preface
    List of journal abbreviations
    Part I. Foundations of Electronic and Photoelectron Spectroscopy:
    1 Introduction
    2. Electronic structure
    3. Angular momentum in spectroscopy
    4. Classification of electronic states
    5. Molecular vibrations
    6. Molecular rotations
    7. Transition probabilities
    Part II. Experimental Techniques:
    8. The sample
    9. Broadening of spectroscopic lines
    10. Lasers
    11. Optical spectroscopy
    12. Photoelectron spectroscopy
    Part III. Case Studies:
    13. Ultraviolet photoelectron spectrum of CO
    14. Photoelectron spectra of CO2, OCS, and CS2 in a molecular beam
    15. Photoelectron spectrum of NO2−
    16. Laser-induced fluorescence spectroscopy of C3: rotational structure in the 300 nm system
    17. Photoionization spectrum of diphenylamine: an unusual illustration of the Franck–Condon principle
    18. Vibrational structure in the electronic spectrum of 1,4-benzodioxan: assignment of low frequency modes
    19. Vibrationally resolved ultraviolet spectroscopy of propynal
    20. Rotationally resolved laser excitation spectrum of propynal
    21. ZEKE spectroscopy of Al(H2O) and Al(D2O)
    22. Rotationally resolved electronic spectroscopy of the NO free radical
    23. Vibrationally resolved spectroscopy of Mg+–rare gas complexes
    24. Rotationally resolved spectroscopy of Mg+–rare gas complexes
    25. Vibronic coupling in benzene
    26. REMPI spectroscopy of chlorobenzene
    27. Spectroscopy of the chlorobenzene cation
    28. Cavity ringdown spectroscopy of the a1∆←X3∑g− transition in O2
    Appendices
    Index.

  • Authors

    Andrew M. Ellis, University of Leicester

    Miklos Feher, Neurocrine Biosciences, San Diego

    Timothy G. Wright, University of Nottingham

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