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Proton Conductors
Solids, Membranes and Gels - Materials and Devices

$118.00 ( ) USD

Part of Chemistry of Solid State Materials

  • Editor: Philippe Colomban, Centre National de la Recherche Scientifique (CNRS), Paris
A. Potier, D. J. Jones, J. Rozière, Ph. Colomban, A. Novak, J. O. Thomas, I. Svare, P. G. Dickens, A. M. Chippindale, H. Iwahara, F. Freund, I. A. Ryzhkin, H. Fuzellier, J. Conard, H. Ikawa, E. Krogh Andersen, I. G. Krogh Anderson, E. Skou, A. Clearfield, G. Alberti, M. Casciola, G. Pourcelly, C. Gavach, J. C. Lassègues, S. V. Bhat, R. Frech, J. C. Badot, K.-D. Kreuer, J. P. Korb, F. Devreux, R. C. T. Slade, P. S. Nicholson, N. Miura, N. Ymazoe, J. Guitton, C. Poinsignon, J. Y. Sanchez, O. Bohnke, M. Pham-Thi
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  • Date Published: February 2011
  • availability: This ISBN is for an eBook version which is distributed on our behalf by a third party.
  • format: Adobe eBook Reader
  • isbn: 9780511831775

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About the Authors
  • The present book covers different aspects of proton conduction: the first part describes chemical and physical parameters necessary for fast proton conduction and proposes a classification of different kinds of proton conductors. Comparison is made with other hydrogen containing materials (metals, graphites). The importance of partial water pressure, the role of defects and surface phenomena are discussed. The second part treats the chemistry, structures and electrical properties of typical materials from hydrogen bronzes to polymers via ice, hydroxides, acid sulphates, layer hydrates, clays, gels and porous or fractal media. The third part discusses the methods concerning the proton dynamics from local to macroscopic scale. The fourth part deals with conductivity mechanisms and the last one presents typical applications: electrochemical systems for production or energy storage and microionic devices.

    • A comprehensive review
    • There is currently much worldwide interest in proton conducting solids
    • Gives many possible applications, including high-density solid-state batteries
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    Product details

    • Date Published: February 2011
    • format: Adobe eBook Reader
    • isbn: 9780511831775
    • contains: 127 b/w illus. 16 tables
    • availability: This ISBN is for an eBook version which is distributed on our behalf by a third party.
  • Table of Contents

    List of contributors
    Preface
    Part I. The Hydrogen Bond and Protonic Species:
    1. The hydrogen bond and chemical parameters favouring proton mobility in solids A. Potier
    2. Protonic species and their structures D. J. Jones and J. Rozière
    3. Proton conductors: classification and conductivity Ph. Colomban and A. Novak
    4. Defects, non-stoichiometry and phase transitions Ph. Colomban and A. Novak
    5. Structural studies of proton conductors J. O. Thomas
    6. Hydrogen in metals: structure, diffusion and tunnelling I. Svare
    Part II. Materials: Preparation, Structures and Properties:
    7. Structure and characterization of hydrogen insertion compounds of metal oxides P. G. Dickens and A. M. Chippindale
    8. High temperature proton conductors based on perovskite-type oxides H. Iwahara
    9. Highly ionic hydroxides: unexpected proton conductivity in Mg(OH)2 and homologues F. Freund
    10. Ice I. A. Ryzhkin
    11. Anhydrous materials: oxonium perchlorate, acid phosphates, arsenates, sulphates and selenates Ph. Colomban and A. Novak
    12. Hydrogen behaviour in graphite-nitric acid intercalation compounds H. Fuzellier and J. Conard
    Section 1. A. Inorganic Ion Exchangers:
    13. Proton-containing ß- and ß"-alumina structure type compounds H. Ikawa
    14. Proton conduction in zeolites E. Krogh Andersen, I. G. Krogh Anderson and E. Skou
    15. Proton containing NASICON phases A. Clearfield
    Section 2. B. Layer Hydrates:
    16. Phosphates and phosphonates of tetravalent metals as protonic conductors G. Alberti and M. Casciola
    17. Hydrogen uranyl phosphate H3OUO2PO4.3H2O (HUP), and related materials Ph. Colomban and A. Novak
    18. From crystalline to amorphous (particle) hydrates: inorganic polymers, glasses, clays, gels and porous media Ph. Colomban and A. Novak
    19. Perfluorinated membranes G. Pourcelly and C. Gavach
    20. Mixed inorganic–organic systems: the acid/polymer blends J. C. Lassègues
    Part III. Proton Dynamics and Charge Transport:
    21. Incoherent neutron scattering studies of proton conductors: from the anhydrous solid state to aqueous solutions J. C. Lassègues
    22. NMR studies of local motions in fast protonic conductors S. V. Bhat
    23. Vibrational spectroscopy of proton conductors Ph. Colomban and A. Novak
    24. Raman spectroscopic studies of proton conductors R. Frech
    25. Frequency dependent conductivity, microwave dielectric relaxation and proton dynamics Ph. Colomban and J. C. Badot
    26. Measuring the true proton conductivity K.-D. Kreuer
    27. D.c. techniques and a.c./d.c. combination techniques E. Skou, I. G. Krogh Andersen and E. Krogh Andersen
    28. NMR in gels and porous media J. P. Korb and F. Devreux
    Part IV. Proton Diffusion Mechanisms:
    29. Mobility in hydrogen-containing oxide bronzes: the atomic-level detail R. C. T. Slade
    30. Conductivity mechanisms and models in anhydrous protonic conductors Ph. Colomban and A. Novak
    31. Conduction mechanisms in materials with volatile molecules K.-D. Kreuer
    Part V. Devices: Section 1. A. Energy Storage and Production:
    32. Applications of perfluorinated proton conductors (Nafions) C. Gavach and G. Pourcelly
    33. Synthesis of polycrystalline H30+ and NH4+ß/ß"Al203 and potential application in steam electrolysis/fuel-cells P. S. Nicholson
    34. Fuel-cells, steam-electrolysis for hydrogen production and hydrogen separation using high temperature protonic conductors H. Iwahara
    Section 2. B. Small Components and Microionic Devices:
    35. Ice-based devices I. A. Ryzhkin
    36. Solid-state gas sensors operating at room temperature N. Miura and N. Ymazoe
    37. All solid-state protonic batteries J. Guitton, C. Poinsignon and J. Y. Sanchez
    38. Applications of proton conductors in electrochromic devices (ECDs) O. Bohnke
    39. Supercapacitors and interfacial charge accumulation devices Ph. Colomban and M. Pham-Thi
    Index.

  • Editor

    Philippe Colomban, Centre National de la Recherche Scientifique (CNRS), Paris

    Contributors

    A. Potier, D. J. Jones, J. Rozière, Ph. Colomban, A. Novak, J. O. Thomas, I. Svare, P. G. Dickens, A. M. Chippindale, H. Iwahara, F. Freund, I. A. Ryzhkin, H. Fuzellier, J. Conard, H. Ikawa, E. Krogh Andersen, I. G. Krogh Anderson, E. Skou, A. Clearfield, G. Alberti, M. Casciola, G. Pourcelly, C. Gavach, J. C. Lassègues, S. V. Bhat, R. Frech, J. C. Badot, K.-D. Kreuer, J. P. Korb, F. Devreux, R. C. T. Slade, P. S. Nicholson, N. Miura, N. Ymazoe, J. Guitton, C. Poinsignon, J. Y. Sanchez, O. Bohnke, M. Pham-Thi

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